Aquabis(1,1,1,5,5,5-hexafluoroacetylacetonato)[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine]ytterbium(III) chloride methanol monosolvate monohydrate

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Aqua­bis­(1,1,1,5,5,5-hexa­fluoro­acetyl­acetonato)[4′-(4-pyrid­yl)-2,2′:6′,2′′-terpyridine]­ytterbium(III) chloride methanol monosolvate monohydrate

The title compound, [Yb(C(5)HF(6)O(2))(2)(C(20)H(14)N(4))(H(2)O)]Cl·CH(3)OH·H(2)O, adopts an eight-coordinated geometry around the Yb(III) atom consisting of a 4'-(4-pyrid-yl)-2,2':6',2''-terpyridine (pytpy) ligand, two 1,1,1,5,5,5-hexa-fluoro-acetyl-acetonate (hfac) anions and an aqua ligand. In the solid state, the compound forms supra-molecular chains running along the b-axis via inter-molec...

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2,4,5-Tri-4-pyridyl-1H-imidazole monohydrate

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In the title compound, C(17)H(18)N(4)O(2)S·CH(3)OH, the two benzene rings in the thio-carbonohydrazide mol-ecule form a dihedral angle of 22.42 (18)°. Pairs of N-H⋯S hydrogen bonds link thio-carbonohydrazide mol-ecules into centrosymmetric dimers. Methanol solvent mol-ecules serve as donors (O-H⋯S and O-H⋯N) and acceptors (N-H⋯O and C-H⋯O) of weak inter-molecular hydrogen bonds, which link furt...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811052378